Carbon dioxide capture with concentrated,aqueous piperazine

Concentrated, aqueous piperazine (PZ) has been investigated as a novel amine solvent for carbon dioxide (CO₂) absorption. The CO₂ absorption rate of aqueous PZ is more than double that of 7 m MEA and the amine volatility at 40 °C ranges from 11 to 21 ppm. Thermal degradation is negligible in concentrated, aqueous PZ up to a temperature of 150 °C, a significant advantage over MEA systems. Oxidation of concentrated, aqueous PZ is appreciable in the presence of copper (4 mM), but negligible in the presence of chromium (0.6 mM), nickel (0.25 mM), iron (0.25 mM), and vanadium (0.1 mM). Initial system modeling suggests that 8 m PZ will use 10–20% less energy than 7 m MEA. The fast mass transfer and low degradation rates suggest that concentrated, aqueous PZ has the potential to be a preferred solvent for CO₂ capture.     

Overlapping defense responses to water limitation and pathogen attack and their consequences for resistance to powdery mildew disease in garlic mustard, Alliaria petiolata

Plant responses to abiotic stress can alter their response to biotic stress. We examined changes in the activity of several defense proteins in response to powdery mildew infection of garlic mustard (Alliaria petiolata) in the greenhouse and in the field. Second, we examined the effects of water limitation on the same defense protein responses, as well as on total soluble protein and glucose concentration, plant growth, and powdery mildew disease development. Similar increases in the activity of peroxidase, chitinase, and β-1-3-glucanase were observed in leaves of plants with substantial powdery mildew disease in both greenhouse- and field-grown plants. In the greenhouse, activities of chitinase and peroxidase as well as total soluble protein and glucose concentrations generally increased with the degree of water limitation. In turn, leaf growth and powdery mildew symptom development decreased as the degree of water limitation increased. This study revealed that plant chemical responses to water limitation and powdery mildew disease can overlap to a large extent, which, in addition to changing microenvironmental conditions and other indicators of plant quality, may underlie the ability of water limitation to inhibit powdery mildew disease symptom development in this wild plant pathosystem.     

Characterizing food waste substrates for co-digestion through biochemical methane potential (BMP) experiments

Co-digestion of food waste with dairy manure is increasingly utilized to increase energy production and make anaerobic digestion more affordable; however, there is a lack of information on appropriate co-digestion substrates. In this study, biochemical methane potential (BMP) tests were conducted to determine the suitability of four food waste substrates (meatball, chicken, cranberry and ice cream processing wastes) for co-digestion with flushed dairy manure at a ratio of 3.2% food waste and 96.8% manure (by volume), which equated to 14.7% (ice-cream) to 80.7% (chicken) of the VS being attributed to the food waste. All treatments led to increases in methane production, ranging from a 67.0% increase (ice cream waste) to a 2940% increase (chicken processing waste) compared to digesting manure alone, demonstrating the large potential methane production of food waste additions compared to relatively low methane production potential of the flushed dairy manure, even if the overall quantity of food waste added was minimal.     

Does Organic Farming Face Distinctive Livestock Welfare Issues? – A Conceptual Analysis

The recent development and growth oforganic livestock farming and the relateddevelopment of national and internationalregulations has fueled discussions amongscientists and philosophers concerning theproper conceptualization of animal welfare.These discussions on livestock welfare inorganic farming draw on the conventionaldiscussions and disputes on animal welfare thatinvolve issues such as different definitions ofwelfare (clinical health, absence of suffering,sum of positive and negative experiences,etc.), the possibility for objective measuresof animal welfare, and the acceptable level ofwelfare. It seems clear that livestock welfareis a value-laden concept and that animalwelfare science cannot be made independent ofquestions of values and ethics. The questioninvestigated here is whether those values thatunderpin organic farming, in particular, alsoaffect the interpretation of livestock welfare,and, if so, how. While some of the issuesraised in connection with organic farming arerelatively uncontroversial, others are not. Theintroduction of organic farming values seems tointroduce new criteria for what counts as goodanimal welfare, as well as a different ethicalbasis for making moral decisions on welfare.Organic farming embodies distinctive systemicor communitarian ethical ideas and the organicvalues are connected to a systemic conceptionof nature, of agriculture, of the farm, and ofthe animal. The new criteria of welfare arerelated to concepts such as naturalness,harmony, integrity, and care. While the organicvalues overlap with those involved in theconventional discussion of animal welfare, someof them suggest a need to set new prioritiesand to re-conceptualize animal welfare – forexample, with respect to ``naturalness,' inrelation to the possibilities for expression ofnatural behavior and in relation to animalintegrity as a concept for organismic harmony.The organic perspective also seems to suggest awider range of solutions to welfare problemsthan changes in farm routines or operations onthe animals. The systemic solutions include thechoice and reproduction of suitable breeds,changes in the farm structure, and changes inthe larger production and consumption system – including consumer perceptions andpreferences. But the organic values may alsocall for sacrifices of individual welfare in aconventional sense in order to advance welfarefrom the perspective of organic farming.Whether this is good or bad cannot be decidedwithout entering into an inquiry and discussionof the values and ethics involved.     

Metallic and organic contaminants in sediments of Sydney Harbour, Australia and vicinity-- a chemical dataset for evaluating sediment quality guidelines

An internally consistent dataset comprising 103 surficial estuarine sediment samples were collected from Sydney Harbour, Australia and locations south of Sydney. This paper describes the chemical characteristics of the dataset and evaluates its suitability for use in evaluating biological effects-based sediment quality guidelines (SQGs). The sediments contained mixtures of chemicals, the most prevalent chemical classes being metals and polycyclic aromatic hydrocarbons, whereas sediments from coastal lakes/estuaries south of Sydney had low concentrations of contaminants. Maximum concentrations of the prevalent contaminants zinc, lead, copper and pyrene were 11,300, 1,420, 1,060 mg kg(-1) and 23,300 microg kg(-1), respectively. For the majority of samples, concentrations of individual chemicals exceeded most effects-based SQGs that have been adopted for use in Australia, implying occasional or frequent adverse biological effects are expected. Comparing mixtures of contaminants to ranges in numbers of SQGs exceeded and mean SQG quotients showed that most samples (57% to 68%) had contamination characteristics associated with moderate probabilities (30% to 52%) of acute toxicity, based on North American data. A smaller proportion of samples (15% to 17%) had contamination characteristics associated with high probabilities (74% to 85%) of toxicity. The wide range of chemicals and concentrations, associated with low, medium and high probabilities of toxicity, indicated that the dataset was suitable for future use in evaluating predictive abilities of SQGs. This is relevant, given the recent introduction of North American-derived SQGs for Australia.     

硼化物基超高温复合陶瓷超高速撞击作用下破坏模式研究

随着各国航天实验和航天器的增加,太空中存在微小碎片垃圾越来越多,对航天器正常运行有着极大的危害。研究弹丸超高速撞击硼化物基复合陶瓷产生的碎片云特性,采用非线性动力学分析软件AUTODYN,利用光滑质点动力学方法对圆柱形弹丸超高速撞击硼化物基超高温复合陶瓷单层板形成的碎片云进行数值模拟,分析相同质量不同速度弹丸撞击靶板的破坏模式,不同质量相同速度弹丸撞击靶板的破坏模式。结果表明在不同速度和质量弹丸撞击靶板的破坏模式中,穿孔半径变化规律为穿孔半径随着弹丸速度和质量的增大而增大。根据不同质量弹丸超高速撞击板靶的穿孔半径变化规律,得到弹丸撞击相同厚度靶板的击穿速度临界值。该结果可为航天器超高速撞击风险评估和防护设计提供了参考。